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Independent Generation of Reactive Intermediates Leads to an Alternative Mechanism for Strand Damage Induced by Hole Transfer in Poly(dA-T) Sequences
Purine radical cations (dA•+ and dG•+) are the primary hole carriers of DNA hole migration owing to their favorable oxidation potential. Much less is known about the reactivity of higher energy pyrimidine radical cations. The thymidine radical cation (T•+) was produced at a defined position in DNA f...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6135700/ https://ncbi.nlm.nih.gov/pubmed/30169029 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05484 |
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