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Enantioselective Total Synthesis of Decytospolide A and Decytospolide B Using an Achmatowicz Reaction

Enantioselective syntheses of decytospolide A and decytospolide B are described here. The current synthesis highlights an Achmatowicz rearrangement of an optically active furanyl alcohol followed by reduction of the resulting dihydropyranone hemiacetal with BF(3)•OEt(2) and Et(3)SiH to provide the s...

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Dettagli Bibliografici
Pubblicato in:Org Biomol Chem
Autori principali: Ghosh, Arun K., Simpson, Hannah M., Veitschegger, Anne M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6128299/
https://ncbi.nlm.nih.gov/pubmed/30083684
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8ob01529e
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