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Enantioselective Total Synthesis of Decytospolide A and Decytospolide B Using an Achmatowicz Reaction
Enantioselective syntheses of decytospolide A and decytospolide B are described here. The current synthesis highlights an Achmatowicz rearrangement of an optically active furanyl alcohol followed by reduction of the resulting dihydropyranone hemiacetal with BF(3)•OEt(2) and Et(3)SiH to provide the s...
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| Udgivet i: | Org Biomol Chem |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6128299/ https://ncbi.nlm.nih.gov/pubmed/30083684 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8ob01529e |
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