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Enantioselective Total Synthesis of Decytospolide A and Decytospolide B Using an Achmatowicz Reaction

Enantioselective syntheses of decytospolide A and decytospolide B are described here. The current synthesis highlights an Achmatowicz rearrangement of an optically active furanyl alcohol followed by reduction of the resulting dihydropyranone hemiacetal with BF(3)•OEt(2) and Et(3)SiH to provide the s...

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Publicat a:Org Biomol Chem
Autors principals: Ghosh, Arun K., Simpson, Hannah M., Veitschegger, Anne M.
Format: Artigo
Idioma:Inglês
Publicat: 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6128299/
https://ncbi.nlm.nih.gov/pubmed/30083684
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8ob01529e
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