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Regiospecific N‐Arylation of Aliphatic Amines under Mild and Metal‐Free Reaction Conditions

A transition metal‐free N‐arylation of primary and secondary amines with diaryliodonium salts is presented. Both acyclic and cyclic amines are well tolerated, providing a large set of N‐alkyl anilines. The methodology is unprecedented among metal‐free methods in terms of amine scope, the ability to...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Purkait, Nibadita, Kervefors, Gabriella, Linde, Erika, Olofsson, Berit
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6120470/
https://ncbi.nlm.nih.gov/pubmed/29956877
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807001
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