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Regiospecific N‐Arylation of Aliphatic Amines under Mild and Metal‐Free Reaction Conditions
A transition metal‐free N‐arylation of primary and secondary amines with diaryliodonium salts is presented. Both acyclic and cyclic amines are well tolerated, providing a large set of N‐alkyl anilines. The methodology is unprecedented among metal‐free methods in terms of amine scope, the ability to...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6120470/ https://ncbi.nlm.nih.gov/pubmed/29956877 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807001 |
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