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Stereospecific Radical-Mediated B(12)-Dependent Methyl Transfer by the Fosfomycin Biosynthesis Enzyme Fom3

Fom3, the antepenultimate enzyme in the fosfomycin biosynthetic pathway in Streptomyces spp., is a class B cobalamin-dependent radical SAM methyltransferase that catalyzes methylation of (5′-cytidylyl)-2-hydroxyethylphosphonate (2-HEP-CMP) to form (5′-cytidylyl)-2-hydroxypropylphosphonate (2-HPP-CMP...

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Pubblicato in:Biochemistry
Autori principali: McLaughlin, Martin I., van der Donk, Wilfred A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6103835/
https://ncbi.nlm.nih.gov/pubmed/29969250
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.8b00616
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