Llwytho...

Evidence for a Sigmatropic and an Ionic Pathway in the Winstein Rearrangement

The spontaneous rearrangement of allylic azides is thought to be a sigmatropic reaction. Presented herein is a detailed investigation into the rearrangement of several allylic azides. A combination of experiments including equilibrium studies, kinetic analysis, density functional theory calculations...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Org Chem
Prif Awduron: Ott, Amy A., Packard, Mary H., Ortuño, Manuel A, Johnson, Alayna, Suding, Victoria P., Cramer, Christopher J., Topczewski, Joseph J
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2018
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC6076873/
https://ncbi.nlm.nih.gov/pubmed/29870252
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b00961
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