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Oxyanionic Sigmatropic Rearrangements Relevant to Cyclooctadienone Formation in Penostatins I and F
[Image: see text] The results of several experiments designed to probe the energetic viability of a reaction path for generation of penostatins I (3) and F (4) via spontaneous [3,3]-sigmatropic rearrangement are reported. In particular, the enolate derived from the 2-vinyl-6-acyldihydropyran 8-cis g...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3501534/ https://ncbi.nlm.nih.gov/pubmed/22963036 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3019488 |
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