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Evidence for a Sigmatropic and an Ionic Pathway in the Winstein Rearrangement
The spontaneous rearrangement of allylic azides is thought to be a sigmatropic reaction. Presented herein is a detailed investigation into the rearrangement of several allylic azides. A combination of experiments including equilibrium studies, kinetic analysis, density functional theory calculations...
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| Veröffentlicht in: | J Org Chem |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6076873/ https://ncbi.nlm.nih.gov/pubmed/29870252 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b00961 |
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