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Novel valdecoxib derivatives by ruthenium(ii)-promoted 1,3-dipolar cycloaddition of nitrile oxides with alkynes – synthesis and COX-2 inhibition activity

Novel valdecoxib-based cyclooxygenase-2 inhibitors were synthesized in one step via 1,3-dipolar cycloaddition of nitrile oxides with a series of eleven aryl alkynes, six of them described for the first time. Application of Ru(ii)-catalysis leads preferably to the formation of the 3,4-diaryl-substitu...

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Publicado en:Medchemcomm
Main Authors: Roscales, Silvia, Bechmann, Nicole, Weiss, Daniel Holger, Köckerling, Martin, Pietzsch, Jens, Kniess, Torsten
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2018
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6072335/
https://ncbi.nlm.nih.gov/pubmed/30108944
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7md00575j
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