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Regioselective Intramolecular Dipolar Cycloaddition of Azides and Unsymmetrical Alkynes

[Image: see text] Enantioenriched allenylsilanes are used in three component propargylation reactions with aldehydes and silyl ethers to form syn-homopropargylic ethers that contain an imbedded azide. These materials then undergo thermally induced intramolecular 1,3-dipolar cycloaddition reactions,...

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Detalhes bibliográficos
Main Authors: Brawn, Ryan A., Welzel, Morgan, Lowe, Jason T., Panek, James S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3164318/
https://ncbi.nlm.nih.gov/pubmed/20017521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902681t
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