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Regioselective Intramolecular Dipolar Cycloaddition of Azides and Unsymmetrical Alkynes

[Image: see text] Enantioenriched allenylsilanes are used in three component propargylation reactions with aldehydes and silyl ethers to form syn-homopropargylic ethers that contain an imbedded azide. These materials then undergo thermally induced intramolecular 1,3-dipolar cycloaddition reactions,...

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Bibliografische gegevens
Hoofdauteurs: Brawn, Ryan A., Welzel, Morgan, Lowe, Jason T., Panek, James S.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2010
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3164318/
https://ncbi.nlm.nih.gov/pubmed/20017521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902681t
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