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Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex
The rebound mechanism for alkane hydroxylation was invoked over 40 years ago to help explain reactivity patterns in cytochrome P450, and subsequently has been used to provide insight into a range of biological and synthetic systems. Efforts to model the rebound reaction in a synthetic system have be...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6058725/ https://ncbi.nlm.nih.gov/pubmed/28930448 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07979 |
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