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Copper-catalyzed direct transformation of simple alkynes to alkenyl nitriles via aerobic oxidative N-incorporation

A novel direct transformation of aliphatic terminal alkynes to alkenyl nitriles through the incorporation of a nitrogen atom into the simple hydrocarbons has been reported. The usage of inexpensive copper catalyst, O(2) as the sole oxidant, broad substrate scope as well as feasibility for “late-stag...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Huang, Xiaoqiang, Li, Xinyao, Jiao, Ning
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6054104/
https://ncbi.nlm.nih.gov/pubmed/30090253
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02126j
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