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Cobalt-Catalyzed, Aminoquinoline-Directed sp(2) C-H Bond Alkenylation by Alkynes()

We have developed a method for cobalt-catalyzed, aminoquinoline- and picolinamide-directed sp(2) C-H bond alkenylation by alkynes. Method shows excellent functional group tolerance and both internal and terminal alkynes are competent substrates for the coupling. The reaction employs Co(OAc)(2)*4H(2)...

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Detalhes bibliográficos
Main Authors: Grigorjeva, Liene, Daugulis, Olafs
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4167400/
https://ncbi.nlm.nih.gov/pubmed/25060365
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201404579
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