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Following the electrons: Peculiarities in the catalytic cycles of Radical SAM enzymes
Radical SAM enzymes use S-adenosyl-L-methionine as an oxidant to initiate radical-mediated transformations that would otherwise not be possible with Lewis acid/base chemistry alone. These reactions are either redox neutral or oxidative leading to certain expectations regarding the role of SAM as eit...
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| Udgivet i: | Nat Prod Rep |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6051909/ https://ncbi.nlm.nih.gov/pubmed/29485151 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7np00058h |
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