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Chiral Brønsted acid-catalyzed intramolecular S(N)2′ reaction for enantioselective construction of a quaternary stereogenic center
An enantioselective intramolecular anti-S(N)2′ cyclization reaction for the construction of a quaternary stereogenic center was accomplished through the activation of the leaving group using a binaphthol-derived phosphoramide as the chiral Brønsted acid catalyst. The present allylic substitution rea...
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| Опубликовано в: : | Chem Sci |
|---|---|
| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Royal Society of Chemistry
2018
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6050593/ https://ncbi.nlm.nih.gov/pubmed/30079184 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01942h |
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