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Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis/trans-Influence on Stability, Insertion Chemistry, and NMR Chemical Shifts
[Image: see text] The synthesis of new families of stable or at least spectroscopically observable gold(III) hydride complexes is reported, including anionic cis-hydrido chloride, hydrido aryl, and cis-dihydride complexes. Reactions between (C^C)AuCl(PR(3)) and LiHBEt(3) afford the first examples of...
Guardat en:
| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical
Society
2018
|
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6047844/ https://ncbi.nlm.nih.gov/pubmed/29860842 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b04478 |
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