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Lewis Acid Activation of the Ferrous Heme–NO Fragment Towards the N–N Coupling Reaction with NO to Generate N(2)O
Bacterial NO reductase (bacNOR) enzymes utilize a heme-nonheme active site to couple two NO molecules to N(2)O. We show that BF(3) coordination to the nitrosyl O-atom in (OEP)Fe(NO) activates it towards N–N bond formation with NO to generate N(2)O. (15)N-isotopic labeling reveals a reversible nitros...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6040813/ https://ncbi.nlm.nih.gov/pubmed/29502400 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b13681 |
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