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Harnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(ll)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-Triazoles
The regioselective and enantioselective intermolecular sp(3) C–H functionalization of silicon-substituted alkanes was accomplished using Rh(2)(S-NTTL)(4) with readily available 1-sulfonyl-1,2,3-triazoles as carbene precursors. These reactions generate a diverse array of stereodefined substituted sil...
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| Publicado no: | Org Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6035867/ https://ncbi.nlm.nih.gov/pubmed/29638130 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b00427 |
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