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Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins with N-Sulfonyl 1,2,3-Triazoles

[Image: see text] N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Chuprakov, Stepan, Kwok, Sen Wai, Zhang, Li, Lercher, Lukas, Fokin, Valery V.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2009
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2801057/
https://ncbi.nlm.nih.gov/pubmed/19928917
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja908075u
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