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Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles

[Image: see text] Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.

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Detalhes bibliográficos
Main Authors: Horneff, Tony, Chuprakov, Stepan, Chernyak, Natalia, Gevorgyan, Vladimir, Fokin, Valery V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2668606/
https://ncbi.nlm.nih.gov/pubmed/18855475
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja805079v
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