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Copper-promoted site-selective carbonylation of sp(3) and sp(2) C–H bonds with nitromethane
Copper-promoted direct carbonylation of unactivated sp(3) C–H and aromatic sp(2) C–H bonds of amides was developed using nitromethane as a novel carbonyl source. The sp(3) C–H functionalization showed high site-selectivity by favoring the C–H bonds of α-methyl groups. The sp(2) C–H carbonylation fea...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6020547/ https://ncbi.nlm.nih.gov/pubmed/30155175 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01087c |
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