Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity

Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7-sulfinylamino-7-azadibenzonorbornadiene (1). This compound has been shown to fragment readily driven by dinitrogen expul...

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Vydáno v:Proc Natl Acad Sci U S A
Hlavní autoři: Joost, Maximilian, Nava, Matthew, Transue, Wesley J., Martin-Drumel, Marie-Aline, McCarthy, Michael C., Patterson, David, Cummins, Christopher C.
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2018
Témata:
Physical Sciences
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6003320/
https://ncbi.nlm.nih.gov/pubmed/29773708
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1804035115
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