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UV spectroscopic determination of the chlorine monoxide (ClO) / chlorine peroxide (ClOOCl) thermal equilibrium constant

The thermal equilibrium constant between the chlorine monoxide radical (ClO) and its dimer, chlorine peroxide (ClOOCl), was determined as a function of temperature between 228 and 301K in a discharge flow apparatus using broadband UV absorption spectroscopy. A third-law fit of the equilibrium values...

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Publicat a:Atmos Chem Phys
Autors principals: Klobas, J. Eric, Wilmouth, David M.
Format: Artigo
Idioma:Inglês
Publicat: 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6800689/
https://ncbi.nlm.nih.gov/pubmed/31632449
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.5194/acp-19-6205-2019
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