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Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent
Formal addition of diazomethane's terminal nitrogen atom to the 9,10-positions of anthracene yields H(2)CN(2)A (1, A = C(14)H(10) or anthracene). The synthesis of this hydrazone is reported from Carpino's hydrazine H(2)N(2)A through treatment with paraformaldehyde. Compound 1 has been foun...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5890322/ https://ncbi.nlm.nih.gov/pubmed/29675198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04506a |
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