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Dehydrogenative coupling of 4-substituted pyridines mediated by a zirconium(ii) synthon: reaction pathways and dead ends
The mechanism of the reductive homocoupling of pyridine derivatives mediated by the Zr(II) synthon [(PNP)Zr(η(6)-toluene)Cl] (1) has been investigated. Selective transformation into three different types of product complexes has been observed, depending on the N-heterocyclic substrate employed: the...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6001252/ https://ncbi.nlm.nih.gov/pubmed/29997877 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01025k |
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