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Cross-dehydrogenative coupling enables enantioselective access to CF(3)-substituted all-carbon quaternary stereocenters
A cross-dehydrogenative coupling strategy for enantioselective access to acyclic CF(3)-substituted all-carbon quaternary stereocenters has been established. By using catalytic DDQ with MnO(2) as an inexpensive terminal oxidant, asymmetric cross coupling of racemic δ-CF(3)-substituted phenols with in...
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| Izdano u: | Chem Sci |
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| Glavni autori: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
The Royal Society of Chemistry
2020
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8157275/ https://ncbi.nlm.nih.gov/pubmed/34084405 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05894j |
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