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Dehydrogenative coupling of 4-substituted pyridines mediated by a zirconium(ii) synthon: reaction pathways and dead ends

The mechanism of the reductive homocoupling of pyridine derivatives mediated by the Zr(II) synthon [(PNP)Zr(η(6)-toluene)Cl] (1) has been investigated. Selective transformation into three different types of product complexes has been observed, depending on the N-heterocyclic substrate employed: the...

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Vydáno v:Chem Sci
Hlavní autoři: Merz, Lukas S., Wadepohl, Hubert, Clot, Eric, Gade, Lutz H.
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6001252/
https://ncbi.nlm.nih.gov/pubmed/29997877
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01025k
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