Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium‐Assisted Multicomponent Reactions

Consecutive C‐ and N‐arylation of N‐heterocyclic nitriles is mediated by titanium(IV) alkoxides. The carbo‐ and azaphilic arylation step may be separated by choosing the order in which the two equivalents of aryl transfer reagent are added. In the course of this transformation, the ancillary N‐heter...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chemistry
Egile Nagusiak: Roth, Torsten, Wadepohl, Hubert, Clot, Eric, Gade, Lutz H.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: WILEY‐VCH Verlag 2015
Gaiak:
Full Papers
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4832833/
https://ncbi.nlm.nih.gov/pubmed/26542982
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201503732
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