Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium‐Assisted Multicomponent Reactions

Consecutive C‐ and N‐arylation of N‐heterocyclic nitriles is mediated by titanium(IV) alkoxides. The carbo‐ and azaphilic arylation step may be separated by choosing the order in which the two equivalents of aryl transfer reagent are added. In the course of this transformation, the ancillary N‐heter...

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Detaylı Bibliyografya
Yayımlandı:Chemistry
Asıl Yazarlar: Roth, Torsten, Wadepohl, Hubert, Clot, Eric, Gade, Lutz H.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: WILEY‐VCH Verlag 2015
Konular:
Full Papers
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4832833/
https://ncbi.nlm.nih.gov/pubmed/26542982
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201503732
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