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A Nonheme, High-Spin {FeNO}(8) Complex that Spontaneously Generates N(2)O
One-electron reduction of [Fe(NO)-(N3PyS)]BF(4) (1) leads to the production of the metastable nonheme {FeNO}(8) complex, [Fe(NO)(N3PyS)] (3). Complex 3 is a rare example of a high-spin (S = 1) {FeNO}(8), and is the first example, to our knowledge, of a mononuclear nonheme {FeNO}(8) species that gene...
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| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2017
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5997263/ https://ncbi.nlm.nih.gov/pubmed/28749673 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b05549 |
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