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The Production of Nitrous Oxide by the Heme/Nonheme Diiron Center of Engineered Myoglobins (Fe(B)Mbs) Proceeds through a trans-Iron-Nitrosyl Dimer

[Image: see text] Denitrifying NO reductases are transmembrane protein complexes that are evolutionarily related to heme/copper terminal oxidases. They utilize a heme/nonheme diiron center to reduce two NO molecules to N(2)O. Engineering a nonheme Fe(B) site within the heme distal pocket of sperm wh...

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Autors principals: Matsumura, Hirotoshi, Hayashi, Takahiro, Chakraborty, Saumen, Lu, Yi, Moënne-Loccoz, Pierre
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4004238/
https://ncbi.nlm.nih.gov/pubmed/24432820
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410542z
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