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Enantioselective Catalyst Systems from Copper(II) Triflate and BINOL–Silanediol()

Silanediol and copper catalysis are merged, for the first time, to create an enhanced Lewis acid catalyst system for enantioselective heterocycle functionalization. The promise of this silanediol and copper catalyst combination is demonstrated in the enantioselective addition of indoles to alkyliden...

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Publicado en:Chemistry
Main Authors: Guan, Yong, Attard, Jonathan W., Visco, Michael D., Fisher, Thomas J., Mattson, Anita E.
Formato: Artigo
Idioma:Inglês
Publicado: 2018
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5996771/
https://ncbi.nlm.nih.gov/pubmed/29575279
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201801304
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