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Selecting Chiral BINOL‐Derived Phosphoric Acid Catalysts: General Model To Identify Steric Features Essential for Enantioselectivity

Choosing the optimal catalyst for a new transformation is challenging because the ideal molecular requirements of the catalyst for one reaction do not always simply translate to another. Large groups at the 3,3′ positions of the binaphthol rings are important for efficient stereoinduction but if the...

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Publicat a:Chemistry
Autors principals: Reid, Jolene P., Goodman, Jonathan M.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5656902/
https://ncbi.nlm.nih.gov/pubmed/28771900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702019
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