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Rhodium Catalyzed Asymmetric Hydrogenation of Unprotected N-H Imines Assisted by Thiourea()
Asymmetric hydrogenation of unprotected N-H imines catalyzed by Rh/bisphosphine-thiourea provided chiral amines with up to 97% yield and 95% ee. (1)H NMR studies, coupled with control experiments, implied that catalytic chloride-bound intermediates were involved in the mechanism via the dual hydroge...
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| Izdano u: | Angew Chem Int Ed Engl |
|---|---|
| Glavni autori: | , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2014
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5989712/ https://ncbi.nlm.nih.gov/pubmed/24939397 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201404570 |
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