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Rational Optimization of Supramolecular Catalysts for the Rhodium‐Catalyzed Asymmetric Hydrogenation Reaction

Rational design of catalysts for asymmetric transformations is a longstanding challenge in the field of catalysis. In the current contribution we report a catalyst in which a hydrogen bond between the substrate and the catalyst plays a crucial role in determining the selectivity and the rate of the...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Daubignard, Julien, Detz, Remko J., Jans, Anne C. H., de Bruin, Bas, Reek, Joost N. H.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6123616/
https://ncbi.nlm.nih.gov/pubmed/28834625
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201707670
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