Rhodium-Catalyzed Asymmetric 1,4-Additions, in Water at Room Temperature, with In-Flask Catalyst Recycling

Using the newly introduced designer surfactant polyethyleneglycol ubiquinol sebacate (PQS), as the platform for micellar catalysis, nonracemic BINAP has been covalently attached and rhodium(I) inserted to form PQS-BINAP-Rh. This species, the first example of a nonracemically-ligated transition metal...

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Main Authors: Lipshutz, Bruce H., Isley, Nicholas A., Moser, Ralph, Ghorai, Subir, Leuser, Helena, Taft, Benjamin R.
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3959788/
https://ncbi.nlm.nih.gov/pubmed/24659941
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201200160
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