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Manipulating Micellar Environments for Enhancing Transition Metal-Catalyzed Cross-Couplings in Water at Room Temperature

The remarkable effects of added salts on the properties of aqueous micelles derived from the amphiphile PTS are described. Most notably Heck reactions run in the presence of NaCl lead to couplings on aryl bromides in water at room temperature. Olefin cross- and ring-closing metathesis reactions run...

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Autors principals: Lipshutz, Bruce H., Ghorai, Subir, Leong, Wendy Wen Yi, Taft, Benjamin R., Krogstad, Daniel V.
Format: Artigo
Idioma:Inglês
Publicat: 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3608412/
https://ncbi.nlm.nih.gov/pubmed/21539384
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo200746y
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