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Palladium-Catalyzed Cross-Coupling of Monochlorosilanes And Grignard Reagents

Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkyl-magnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si–Cl...

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Bibliographic Details
Published in:ACS Catal
Main Authors: Vulovic, Bojan, Cinderella, Andrew P., Watson, Donald A.
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5984048/
https://ncbi.nlm.nih.gov/pubmed/29868244
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b03465
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