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Palladium-Catalyzed Cross-Coupling of Monochlorosilanes And Grignard Reagents
Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkyl-magnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si–Cl...
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| Publicado no: | ACS Catal |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5984048/ https://ncbi.nlm.nih.gov/pubmed/29868244 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b03465 |
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