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Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction

We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to...

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Bibliografiska uppgifter
I publikationen:J Am Chem Soc
Huvudupphovsmän: Cinderella, Andrew P., Vulovic, Bojan, Watson, Donald A.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2017
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5531279/
https://ncbi.nlm.nih.gov/pubmed/28570065
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b04364
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