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Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction

We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Cinderella, Andrew P., Vulovic, Bojan, Watson, Donald A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5531279/
https://ncbi.nlm.nih.gov/pubmed/28570065
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b04364
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