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Iron‐catalyzed Cross‐Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes
Presented herein is a mild, facile, and efficient iron‐catalyzed synthesis of substituted allenes from propargyl carboxylates and Grignard reagents. Only 1–5 mol % of the inexpensive and environmentally benign [Fe(acac)(3)] at −20 °C was sufficient to afford a broad range of substituted allenes in e...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4797716/ https://ncbi.nlm.nih.gov/pubmed/26890161 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511139 |
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