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Iron‐catalyzed Cross‐Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes

Presented herein is a mild, facile, and efficient iron‐catalyzed synthesis of substituted allenes from propargyl carboxylates and Grignard reagents. Only 1–5 mol % of the inexpensive and environmentally benign [Fe(acac)(3)] at −20 °C was sufficient to afford a broad range of substituted allenes in e...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Kessler, Simon N., Bäckvall, Jan‐E.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797716/
https://ncbi.nlm.nih.gov/pubmed/26890161
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511139
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