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Direct Observation of the Oxidation of DNA Bases by Phosphate Radical Formed under Radiation: A Model of Backbone-to-base Hole Transfer
In irradiated DNA, by base-to-base and backbone-to-base hole transfer processes, the hole (i.e., the unpaired spin) localizes on the most electropositive base, guanine. Phosphate radicals formed via ionization events in DNA-backbone must play an important role in the backbone-to-base hole transfer p...
Enregistré dans:
| Publié dans: | Phys Chem Chem Phys |
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| Auteurs principaux: | , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5976554/ https://ncbi.nlm.nih.gov/pubmed/29786710 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cp00352a |
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