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Determination of the Cu(III)–OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger’s Rule

The stretching frequency, ν(Cu–O), of the [CuOH](2+) core in the complexes LCuOH (L = N,N′-bis(2,6-diisopropyl-4-R-phenyl)pyridine-2,6-dicarboxamide, R = H or NO(2), or N,N′-bis(2,6-diisopropylphenyl)-1-methylpiperidine-2,6-dicarboxamide) was determined to be ~630 cm(−1) by resonance Raman spectrosc...

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Bibliografische gegevens
Gepubliceerd in:J Am Chem Soc
Hoofdauteurs: Spaeth, Andrew D., Gagnon, Nicole L., Dhar, Debanjan, Yee, Gereon M., Tolman, William B.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2017
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5975256/
https://ncbi.nlm.nih.gov/pubmed/28319386
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00210
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