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Determination of the Cu(III)–OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger’s Rule
The stretching frequency, ν(Cu–O), of the [CuOH](2+) core in the complexes LCuOH (L = N,N′-bis(2,6-diisopropyl-4-R-phenyl)pyridine-2,6-dicarboxamide, R = H or NO(2), or N,N′-bis(2,6-diisopropylphenyl)-1-methylpiperidine-2,6-dicarboxamide) was determined to be ~630 cm(−1) by resonance Raman spectrosc...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5975256/ https://ncbi.nlm.nih.gov/pubmed/28319386 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00210 |
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