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Effects of Charged Ligand Substituents on the Properties of the Formally Copper(III)-Hydroxide ([CuOH](2+)) Unit
With the goal of understanding how distal charge influences the properties and hydrogen atom transfer (HAT) reactivity of the [CuOH](2+) core proposed to be important in oxidation catalysis, the complexes [M](3)[(SO3)LCuOH] (M = [K(18-crown-6)](+) or [K(crypt-222)](+)) and [(NMe3)LCuOH]X (X = BAr(F)...
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| Veröffentlicht in: | Inorg Chem |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6653640/ https://ncbi.nlm.nih.gov/pubmed/30070473 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b01529 |
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