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Effects of Charged Ligand Substituents on the Properties of the Formally Copper(III)-Hydroxide ([CuOH](2+)) Unit

With the goal of understanding how distal charge influences the properties and hydrogen atom transfer (HAT) reactivity of the [CuOH](2+) core proposed to be important in oxidation catalysis, the complexes [M](3)[(SO3)LCuOH] (M = [K(18-crown-6)](+) or [K(crypt-222)](+)) and [(NMe3)LCuOH]X (X = BAr(F)...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Inorg Chem
Egile Nagusiak: Dhar, Debanjan, Yee, Gereon M., Tolman, William B.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2018
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6653640/
https://ncbi.nlm.nih.gov/pubmed/30070473
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b01529
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