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Chemo- and regioselective oxygenation of C(sp(3))–H bonds in aliphatic alcohols using a covalently bound directing activator and atmospheric oxygen
Chemically reactive directing groups (directing activators) represent a promising strategy for mild and regioselective C(sp(3))–H functionalization. The use of a radical N-oxyl directing activator promoted the aerobic oxygenation of benzylic, propargylic, tertiary, and unactivated acyclic methylene...
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| 發表在: | Chem Sci |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2016
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5965247/ https://ncbi.nlm.nih.gov/pubmed/29899913 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04476f |
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