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Trimethylsilyl-Protected Alkynes as Selective Cross Coupling Partners in Ti-Catalyzed [2+2+1] Pyrrole Synthesis
Trimethylsilyl (TMS)-protected alkynes serve as selective alkyne cross coupling partners in Ti-catalyzed [2+2+1] pyrrole synthesis. Reactions of TMS-protected alkynes with internal alkynes and azobenzene catalyzed by Ti imido catalysts yield pentasubstituted 2-TMS-pyrroles with greater than 90% sele...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5964026/ https://ncbi.nlm.nih.gov/pubmed/29573100 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201800595 |
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