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Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles
The combination of VCl(3)(THF)(3) and N,N-bis(trimethylsilyl)aniline (1a) is an efficient catalyst for the [2+2+1] coupling reaction of alkynes and azobenzenes, giving multisubstituted pyrroles. A plausible reaction mechanism involves the generation of a mono-(imido)vanadium(III) species as an initi...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6460926/ https://ncbi.nlm.nih.gov/pubmed/30731038 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13390 |
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