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Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the N=N Bond of 2,2′-Azopyridine: Precursors for Early–Late Heterobimetallic Complexes
We report the syntheses of 2-pyridylimido complexes of tantalum and niobium by N=N bond cleavage of 2,2′-azopyridine. Reaction of MCl(5) (M = Ta and Nb) with 2,2′-azopyridine in the presence of 0.5 equiv of 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene (abbreviated Si-Me-CHD) afforded a dark r...
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| Publicat a: | Inorg Chem |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7017918/ https://ncbi.nlm.nih.gov/pubmed/31553585 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02043 |
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