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Oxidative Nitrene Transfer from Azides to Alkynes via Ti(II)/Ti(IV) Redox Catalysis: Formal [2+2+1] Synthesis of Pyrroles
Catalytic oxidative nitrene transfer from azides with the early transition metals is rare, and has not been observed without the support of redox noninnocent spectator ligands. Here, we report the formal [2+2+1] coupling of azides and alkynes via Ti(II)/Ti(IV) redox catalysis from simple Ti halide i...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6008247/ https://ncbi.nlm.nih.gov/pubmed/29796510 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc02623h |
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